Bringing Groundwater
Quality Research to the
Watershed Scale

Edited by Neil R. Thomson

IAHS Publ. 297 (July 2005) ISBN 1-901502-18-X,
576 + xiv pp. Price £85.00

Sustainable economic growth requires plentiful supplies of high-quality water. This has placed pressure on groundwater resources globally and forced the international groundwater science, engineering and regulatory community to recognize the current limitations of research and resource management. Integrated and technically feasible approaches tackling local issues and watershed-scale concerns concurrently are required. These were considered by GQ2004 (Waterloo, Canada) and this collection of papers comprises a reviewed selection from the conference.

Abstracts of the papers in this volume can be seen at:

www.iahs.info

with information about other IAHS publications and IAHS activities

The introductory contributions include global and several national perspectives, followed by sections dealing with:

– Contaminant input processes

– Site characterization

– Management and decision making

– Natural attenuation processes and applications

– In situ remediation

– Flow and transport modelling at the national, the watershed and smaller scales

Contents

Preface
by Neil R. Thomson & James F. Barker

v

1

Groundwater Quality

 

A global inventory of groundwater quality: first results
Jasper Griffioen, Rianne Brunt, Slavek Vasak & Jac Van Der Gun

3

Groundwater quality in Canada: a national overview
Suzanne Lesage

11

Cumulative factors affecting groundwater quality in domestic wells in Finland
Kirsti Korkka-Niemi

19

Urbanization of rural watersheds in the region of Waterloo: implications for water quality
Randy L. Stotler, Jon Paul Jones, Shaun K. Frape, Robert J. Drimmie, Craig T. Johnston & Ian Judd-Henry

29

Burial sites and their impact on groundwater
Julian Trick, Ben Klinck, Patricia Coombs, Dave Noy & Geoff Williams

36

Quality of water from hand-dug wells, boreholes, and streams in two localities in southwest Nigeria: implications for incidence of water borne diseases
Samson Ayanlaja, O. O. Kehinde-Phillips, Francis Ogunkolo, Bunmi Dada & B. A. Senjobi

44

Groundwater quality trend detection at the regional scale: effects of spatial and temporal variability
H. P. Broers, J. Rozemeijer, M. Van De Aa, B. Van Der Grift & E. A. Buijs

50

2

Contaminant Input Processes

 

Evaluating diffuse groundwater pollution trends—a key challenge for the new EC water directives
Stephen Foster

63

Indicators for assessing transport of oil sands process-affected waters
Michael MacKinnon, Grey Kampala, Bill Marsh, Phil Fedorak & Selma Guigard

71

Herbicide runoff on a pastoral hill slope—a case study
Karin Müller, Roland Stenger & Anis Rahman

81

Dynamics of groundwater recharge through structured soils and the influence on water quality
Edwin Cey, David Rudolph & René Therrien

89

Assessing water travel times during riverbank filtration
Melissa Dawe & Kerry MacQuarrie

97

Investigating surface water–groundwater interactions with the help of sewage indicators in Berlin, Germany
Gudrun Massmann, Uwe Dünnbier, Janek Greskowiak, Andrea Knappe & Asaf Pekdeger

103

Fate and transport of phage as surrogates for viral pathogens in UK aquifers
Eadaoin Joyce, Katie Collins, Aidan Cronin, Joerg Rueedi, Steve Pedley, Alwyn Hart, John Tellam & Richard Greswell

113

Effects of macropore flow on solute transport in a vadoze zone under repetitive rainfall events
Fumi Sugita, Tokuo Kishii & Michael English

122

Factors controlling the chemistry of shallow groundwater in different geological and hydrological environments
Irén Varsányi, Hélène Pauwels & Lajos Ó.Kovács

130

Impact of a polluted stream on its adjacent aquifer: the case of the Alamar zone, Tijuana, Mexico
Fernando T. Wakida, Luis E. Ponce-Serrano, Eulalia Mondragon-Silva, E. Garcia-Flores, David N. Lerner & Guillermo Rodríguez-Ventura

141

The influence of relative permeability heterogeneity on DNAPL releases
G. P. Grant, J. I. Gerhard & B. H. Kueper

148

3

Site Characterization

 

Characterization of Quaternary gravel aquifers and their implementation in hydrogeological models
Uli Maier, Andreas Becht, Boris Kostic, Claudius Bürger, Peter Bayer, Georg Teutsch & Peter Dietrich

159

Geostatistical evaluation of high frequency hydraulic property and groundwater quality data collected by the Waterloo Profiler
Shane McDonald, Jeff Groncki & Susanne Biteman

169

Quantification of PCE mass flow rates for source zone identification
Sebastian Bauer, Marti Bayer-Raich, Christian Kolesar, Dietmar Müller, Thomas Holder & Thomas Ptak

176

Characterization of transport processes in a heterogeneous aquifer using electrical resistivity tomography (ERT)
Kerstin Müller, Jan Vanderborght, Andreas Englert, Andreas Kemna & Harry Vereecken

182

Contaminant retardation by double-porosity diffusive exchange in the Chalk: implications for monitoring
William Burgess, John Barker, Sally Watson & Ben Fretwell

191

Real and apparent thickness relationship for gasoline and gasohol contamination
Alexandra Finotti, Nelson Caicedo, Everton De Oliveira & José Luiz Zoby

197

Detection and characterization of a vinyl chloride plume inside an urbanized area
Alessandro Gargini & Monica Pasini

203

Wettability effects on the natural remobilization of mixed DNAPL pools
James W. Roy, James E. Smith & Robert W. Gillham

212

4

Management and Decision Making

 

Impacts of changing agricultural land-use practices on municipal groundwater quality: Woodstock, Ontario
Claus P. Haslauer, David L. Rudolph, Neil R. Thomson, Rob Walton & Margaret Misek-Evans

223

Developing a farm wellhead protection plan
Hugh Simpson & James Myslik

234

Managing basin-wide groundwater quality changes resulting from enhanced groundwater recharge programs
N. Thomas Sheahan, W. Greg Hamer & David S. Gould

241

Risk-based design of cost-efficient remediation strategies at megasites
Fabio Serapiglia, Judith Sievers & Michael Finkel

249

IMS—A risk-based management approach for megasites, example Bitterfeld megasite, Germany
Jochen Großmann, Judith Sievers, Antje Ritter & Martin Keil

256

Macro and micro scale evaluation of contaminant plumes at Aberdeen Proving Ground
Donald J. Green

262

5

Natural Attenuation Processes and Applications

 

SIReN: Site for innovative research on monitored natural attenuation
Sarah Macnaughton, Richard Swannell, Gordon Lethbridge, Philippa Scott, Graham Norris, Nicola Harries, Alwyn Hart & Jonathan Smith

269

Assessing measurements of first-order degradation rates through the virtual aquifer approach
Sebastian Bauer, Christof Beyer & Olaf Kolditz

274

Investigations of a large TCE plume discharging to surface water
Steven Chapman, Beth Parker & John Cherry

282

Assessment of stable carbon isotopes as a tool for assessing MTBE biodegradation at a field site
Luis E. Lesser, Gerard Spinnler, Paul C. Johnson & Ramon Aravena

290

Natural attenuation of volatile hydrocarbons in the unsaturated zone—modelling for the Værløse field site
Uli Maier, Uli Mayer & Peter Grathwohl

296

Fate and transport of naphthenic acids in groundwater
Francoise Gervais & James Barker

305

Wetlands as natural reactive barriers: the hydrological and geomorphological landscape perspective
Seiichiro Ioka & Norio Tase

311

Steady state plumes: transverse mixing in aquifers, numerical experiments and field scale predictions for natural attenuation
Uli Maier, Hermann Rügner & Peter Grathwohl

317

Modelling a controlled-sourced, multichemical plume undergoing natural attenuation
Caitlin Martin, Hugh McCreadie, John W. Molson & Jim Barker

326

Tracing landfill leachate impacts on groundwater using DOC geochemistry and δ13C measurements
Hossein Mohammadzadeh, Ian Clark & Gilles St-Jean

332

Natural attenuation of N-S-O heteroaromatic compounds in groundwater: chemical analyses, reactive transport experiments and field studies
Matthias Piepenbrink, Martina Krüger, Thomas Ptak & Peter Grathwohl

338

6

In Situ Remediation

 

In situ groundwater clean-up of MTBE by photocatalysis
May Chan, Alex Orlov, Richard Lambert & Rod Lynch

349

Spatial variations in MTBE-biodegradation activity near a biobarrier in Port Hueneme, California
Luis E. Lesser & Paul C. Johnson

358

Sequential reactive barrier remediation of ammonium-contaminated groundwater using polymer mats
Bradley M. Patterson, Michelle E. Grassi, Blair Robertson, Gregory B. Davis & Allan J. McKinley

367

Separating the kinetic and sorption parameters of nitroaromatic compounds in contact with granular iron
Melissa Marietta & John F. Devlin

376

Investigation of the performance of organic carbon permeable reactive barriers using dissolved gas analysis
Randi L. Williams, K. Ulrich Mayer, Rich T. Amos, David W. Blowes & Carol J. Ptacek

383

Adsorption of natural organic matter and its effects on TCE degradation by iron PRBs
Stefano Marconetto, Lai Gui & Robert Gillham

389

In situ chemical oxidation test of organic solvents with potassium permanganate
Salvador Jordana, Jordi Guimerà, Josep A. Domènec & Josep M. Subirana

398

A meso-scale constructed wetland for the remediation of chlorobenzene contaminated groundwater
Arno Kaschl, Andrea Schultz, Carsten Vogt, Falk Dorusch, Peter Popp, Helko Borsdorf, Eberhard Küster, Peter Kuschk, Matthias Kästner & Holger Weiß

404

On-site landfill leachate management in a headwater catchment
Brian Beatty & Joanne Thompson

412

Surfactant enhanced air sparging in Borden sand
Gordon H. Brown, Michael D. Annable, Jaehyun Cho & Heonki Kim

418

Remediation of bromate contaminated groundwater
Ray Butler, E. Cartmell, A. Godley & L. Lytton

426

Remediation of groundwater contaminated by trichloroethylene using groundwater extraction and effects of natural attenuation
Nobuyuki Egusa, Tatemasa Hirata, Masanori Yoshioka & Osami Nakasugi

433

7

Flow and Transport Modelling

 

Pesticide transport in groundwater at the national scale: coupling an unsaturated zone model with a groundwater flow model
Aaldrik Tiktak, Ton Van Der Linden & Gerard Uffink

441

Stochastic modelling of well head protection zones in highly heterogeneous aquifers
Monica Riva, Laura Guadagnini, Eugeniu Martac & Thomas Ptak

449

An adaptive hybrid method of characteristics technique for solving solute transport problems
Jianmei Cheng, Danhong Huang & Jianming Chen

458

Modelling groundwater/surface water interactions using MODFLOW-WhaT
R. Brad Thoms & R. L. Johnson

466

A fully-coupled approach to evaluate the effectiveness of tile-drain systems to control drainage water and salinity
George B. Matanga, Claire Jacquemin & Don Demarco

473

How old is the water? Simulating groundwater age at the watershed scale
J. W. Molson & E. O. Frind

482

Large-scale groundwater flow and transport modelling: methodology and application to the Meuse Basin, Belgium
Philippe Orban, Serge Brouyere, Horatiu Corbeanu & Alain Dassargues

489

Delineation of well head protection areas for wells in Urmia Plain, Iran, using WhAEM2000
K. Badv & M. Deriszadeh

496

Surface and groundwater qualities in an urbanized catchment: scenario from a developing country
Moshood N. Tijani & Shin-Ichi Onodera

506

Applying a laboratory-scale biodegradation concept to model field-scale reactive transport with advanced numerical methods
Sascha E. Oswald, Ian A. Watson, Roger S. Crouch & Steven A. Banwart

517

Numerical simulation of density-driven permanganate oxidation of trichloroethylene DNAPL in a sandy aquifer
Thomas H. Henderson, K. Ulrich Mayer, Beth L. Parker & Tom A. Al

525

An object-oriented groundwater/river model
Olaf Kolditz, Martin Beinhorn & Rudolf Liedl

531

 

 

Key word index

541

Author index

545